<sup>31</sup>P nuclear spin singlet lifetimes in a system with switchable magnetic inequivalence: experiment and simulation
نویسندگان
چکیده
31 P NMR nuclear spin singlet order is reported for the first time. Experiments and molecular dynamics simulations indicate that relaxes primarily via chemical shift anisotropy at high magnetic field strengths.
منابع مشابه
Dependence of nuclear spin singlet lifetimes on RF spin-locking power.
We measure the lifetime of long-lived nuclear spin singlet states as a function of the strength of the RF spin-locking field and present a simple theoretical model that agrees well with our measurements, including the low-RF-power regime. We also measure the lifetime of a long-lived coherence between singlet and triplet states that does not require a spin-locking field for preservation. Our res...
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a Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St., Cambridge, MA 02138 b Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138 c Department of Physics, Harvard University, 17 Oxford St., Cambridge, MA 02138 d Harvard Medical School, 25 Shattuck Street, Boston, MA 02115 e Martinos Center for Biomedical Imaging, 149 Thirteenth St., Charles...
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ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2021
ISSN: ['1463-9076', '1463-9084']
DOI: https://doi.org/10.1039/d1cp03085j